HRID1645206

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID253877

Potassium bromide

BrK

结构：CCCCCCN(Cc1nc2ccccc2[nH]1)Cc1nc2ccccc2[nH]1

HCID66775281

未命名化合物

结构：[Cl-].[Cl-].[Cl-].[Cr+3].c1ccc2[nH]c(CNCc3nc4ccccc4[nH]3)nc2c1

HCID86638460

未命名化合物

PRODUCTS

生成物

结构：CN(Cc1nc2ccccc2[nH]1)Cc1nc2ccccc2[nH]1.[Cl-].[Cl-].[Cl-].[Cr+3]

HCID86638459

未命名化合物

PROCEDURE

实验过程

3b was synthesised by an analogous procedure to that described for 3a using 2e (1 g, 2.8 mmol) and CrCl3(THF)3 (1.05 g, 2.8 mmol). Yield 1.35 g, 93%. Anal. Calc. for C22H27Cl3CrN5 (in %): C, 50.83; H, 5.24; N, 13.47. Found C, 51.05; H, 5.30; N, 13.38. IR (KBr, cm−1), υ 3502 (NH, m), υ 1621-1527 (ArC═C, C═N, m), δ 1498, 1477, 1431 (N—H, s), υ 1273 (CN, m), δ 751 (CH, s). +FAB-MS: (m/z): 483 ([M-Cl]+), 448 ([M-2Cl]).