HRID1645212
反应详情
EQUATION
反应方程式
REACTANTS
反应物
PRODUCTS
生成物
AUXILIARIES
试剂、催化剂与溶剂
PROCEDURE
实验过程
4b was synthesised by an analogous procedure to that described for 4a using silver hexafluoroantimonate (0.762 g, 2.22 mmol) and complex 3b (1 g, 2.22 mmol). Yield 1.09 g, 72%. Anal. Calc. for C21H25Cl2CrF6N5OSb: C, 34.93; H, 3.49; N, 9.70. Found C, 34.89; H, 3.58; N, 9.58. IR (cm−1), υ 3220 (NH, s), υ 3050 (Ar—H, s), υ 1597 (ArC═C, m), δ 1480, 1457 (N—H, m), υ 1277 (CN, m), δ 753 (CH, s), υ 664 (Sb—F, s). FAB(+) mass spectrum, m/z 413 [M+-THF], 378 ([M+-Cl, THF], 288 [M+-Cr(THF)C2]. FAB(−) mass spectrum, m/z 235 [M−]. μeff·=3.77 MB.