Barium Carbonate → HCID 16228711, compound

HRID 1646010Notes

Reaction equation

HRID 1646010 reaction equation
[N:1]12[CH2:11][S:10][CH2:9][CH:8]1[CH2:7][CH:6]1[CH:2]2[CH2:3][N:4](C(OCC)=O)[CH2:5]1.C(=O)([O-])[O-].[K+].[K+].C(=O)([O-])[O-].[Ba+2]>O>[N:1]12[CH2:11][S:10][CH2:9][CH:8]1[CH2:7][CH:6]1[CH:2]2[CH2:3][NH:4][CH2:5]1

Participants

5

Reactant 3

HCID 10563Barium CarbonateHCID 11430Potassium CarbonateHCID 54120114HCID 54120114, compound

Product 1

HCID 16228711HCID 16228711, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

12.5 g (50 mmol) of ethyl 10-thia-1,4-diazatricyclo[6.3.0.02,6 ]undecane-4-carboxylate are heated under reflux overnight with 32 g of Ba(OH)2.8H2O in 225 ml of water. Potassium carbonate is added to the mixture, barium carbonate is filtered off with suction and the filtrate is extracted ten times using 100 ml of chloroform each time. The extracts are dried over potassium carbonate and concentrated, and the residue is distilled.

Workup

  1. filtrationis filtered off with suction
  2. extractionthe filtrate is extracted ten times
  3. dry with materialThe extracts are dried over potassium carbonate
  4. concentrationconcentrated
  5. distillationthe residue is distilled

Sources & evidence

ORD record
ord-792ebffac708475fba81ca946543f2d7
Source dataset
uspto-grants-1993_01
Patent number
US05177210

Reaction notes

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