HCID 15171982, compound → HCID 15171984, compound

HRID 1646184Notes

Reaction equation

HRID 1646184 reaction equation
[CH2:1]([O:3][P:4]([CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([CH2:16][C:17]#[N:18])[CH:11]=1)(=[O:8])[O:5][CH2:6][CH3:7])[CH3:2]>N.[Ni]>[CH2:6]([O:5][P:4]([CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([CH2:16][CH2:17][NH2:18])[CH:11]=1)(=[O:8])[O:3][CH2:1][CH3:2])[CH3:7]

Participants

4

Reactant 1

HCID 15171982HCID 15171982, compound

Product 1

HCID 15171984HCID 15171984, compound

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 222AmmoniaSolvent

Procedure

A solution of diethyl[[3-(cyanomethyl)phenyl]methyl]phosphonate in methanolic ammonia is reduced under a hydrogen atmosphere (50 psi) with Raney nickel as catalyst. The solvent is evaporated to give an oil (4.1 g).

Workup

  1. customThe solvent is evaporated

Sources & evidence

ORD record
ord-cb430c6a2dfa44249f11c8a14a2eb05f
Source dataset
uspto-grants-1993_01
Patent number
US05179085

Reaction notes

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