HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Cyanide → HCID 10487035, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Cyanide | HCID 768 | — |
| Reactant | Isophorone | HCID 6544 | — |
| Reactant | 3-Cyano-3,5,5-trimethylcyclohexanone | HCID 99068 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 10487035 | HCID 10487035 | 70% |
Reaction Steps
West German Patent No. 1,240,854 discloses a method for synthesizing 3-cyano-3,5,5-trimethyl cyclohexanone by causing isophorone to react with hydrogen cyanide in the presence of an alkali metal salt as a catalyst with methanol used as a dispersant for the catalyst. When this method was replicated, however, it was found that the reaction produced 3-cyano-3,5,5-trimethyl cyclohexane only in a low yield of about 70% and entailed by-production of a large amount of polymer of hydrogen cyanide. Thus, this method is problematic as a commercial process.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05179221 |
| Source dataset | uspto-grants-1993_01 |
| ORD ID | ord-f8f3e76515ee4b0c8234963ae60a9d86 |
| Source note | uspto-grants-1993_01 |