Hydroquinone → HCID 12940614, compound

HRID 1648774Notes

Reaction equation

HRID 1648774 reaction equation
[C:1]1([CH:8]=[CH:7][C:5]([OH:6])=[CH:4][CH:3]=1)[OH:2].[F:9][C:10]([F:19])([F:18])[C:11]1[CH:12]=[C:13](Cl)[CH:14]=[CH:15][CH:16]=1>[Cu]>[F:9][C:10]([F:19])([F:18])[C:11]1[CH:12]=[CH:13][CH:14]=[C:15]([O:2][C:1]2[CH:8]=[CH:7][C:5]([OH:6])=[CH:4][CH:3]=2)[CH:16]=1

Participants

4

Reactant 2

HCID 785HydroquinoneHCID 73743-Chlorobenzotrifluoride

Product 1

HCID 12940614HCID 12940614, compound

Reagents, catalysts & solvents 1

HCID 23978CopperCatalyst

Procedure

In an analogous manner to that described in the preceding paragraph, hydroquinone and 3-trifluoromethyl-chlorobenzene in the presence of a catalytic amount of copper powder yield p-(α,α,α-trifluoro-m-tolyloxy)-phenol which distils in the bulb-tube at 140° C./0.05 Torr; nD20 =1.5370.

Sources & evidence

ORD record
ord-1049fc4fa6d6483796e842e18db916b8
Source dataset
uspto-grants-1983_11
Patent number
US04413010

Reaction notes

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