Triethylamine → Methylthiomethyl Tiglate

HRID 1648901Notes

Reaction equation

HRID 1648901 reaction equation
[C:1]([OH:7])(=[O:6])/[C:2](=[CH:4]/[CH3:5])/[CH3:3].[CH3:8][S:9][CH2:10]Cl.C(N(CC)CC)C>>[C:1]([O:7][CH2:8][S:9][CH3:10])(=[O:6])/[C:2](=[CH:4]/[CH3:5])/[CH3:3]

Participants

4

Reactant 3

HCID 8471TriethylamineHCID 16916Chloromethyl methyl sulfideHCID 125468Tiglic acid

Product 1

HCID 11008217Methylthiomethyl Tiglate

Procedure

This product was prepared according to the procedure described in Example 1, by reacting tiglic acid with chloromethyl methyl sulfide in the presence of one equivalent of triethylamine; b.p. 95° C./12 mm Hg, n20 1.4890.

Workup

  1. customThis product was prepared

Sources & evidence

ORD record
ord-7842a152040644c48371c97dee9f7116
Source dataset
uspto-grants-1983_11
Patent number
US04414233

Reaction notes

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