Triethylamine → Methylthiomethyl Geranate

HRID 1648907Notes

Reaction equation

HRID 1648907 reaction equation
[C:1]([OH:12])(=[O:11])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:10])[CH3:9])\[CH3:4].[CH3:13][S:14][CH2:15]Cl.C(N(CC)CC)C>>[C:1]([O:12][CH2:13][S:14][CH3:15])(=[O:11])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:9])[CH3:10])\[CH3:4]

Participants

4

Reactant 3

HCID 8471TriethylamineHCID 16916Chloromethyl methyl sulfideHCID 5275520Geranic acid

Product 1

HCID 86738396Methylthiomethyl Geranate

Procedure

This product was prepared according to the procedure described in Example 1, by reacting geranic acid with chloromethyl methyl sulfide in the presence of one equivalent of triethylamine; b.p. 111°-112° C./2 mm Hg, n20 1.4912.

Workup

  1. customThis product was prepared

Sources & evidence

ORD record
ord-71fbd4cf77f74978b6eb177cb7227d38
Source dataset
uspto-grants-1983_11
Patent number
US04414233

Reaction notes

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