Butylamine → HCID 13138304, compound

HRID 1649076Notes

Reaction equation

HRID 1649076 reaction equation
[NH2:1][C:2]1[N:7]=[C:6](Cl)[N:5]=[C:4]([C:9]2[CH:14]=[CH:13][C:12]([Cl:15])=[C:11]([Cl:16])[CH:10]=2)[N:3]=1.[CH2:17]([NH2:21])[CH2:18][CH2:19][CH3:20]>O1CCOCC1>[NH2:1][C:2]1[N:7]=[C:6]([NH:21][CH2:17][CH2:18][CH2:19][CH3:20])[N:5]=[C:4]([C:9]2[CH:14]=[CH:13][C:12]([Cl:15])=[C:11]([Cl:16])[CH:10]=2)[N:3]=1

Participants

4

Reactant 2

HCID 8007ButylamineHCID 12852449HCID 12852449, compound

Product 1

HCID 13138304HCID 13138304, compoundYield 80.6%

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

2-Amino-4-chloro-6-(3,4-dichlorophenyl)-s-triazine (melting point 249° to 250° C.) (2.75 grams) and 2.0 grams of n-butylamine were heated to reflux with stirring for four hours in 25 milliliters of dioxane. The reaction solution was evaporated to dryness in vacuo, the residue was washed with water and then with methanol, and 2.51 grams of 2-amino-4-butylamino-6-(3,4-dichlorophenyl)-s-triazine was obtained. Melting point 176° to 179° C.

Workup

  1. temperatureto reflux
  2. customThe reaction solution was evaporated to dryness in vacuo
  3. washthe residue was washed with water

Sources & evidence

ORD record
ord-ac4b8ccb993a4ab19f989ab010bc75a0
Source dataset
uspto-grants-1983_11
Patent number
US04415570

Reaction notes

Loading…