HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromo-5-nitropyridine → 2-[3-[(6-Bromohexyl)oxy]-1-propynyl]-5-nitropyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Bromo-5-nitropyridine | HCID 78240 | — |
| Reactant | 1-Bromo-6-(prop-2-YN-1-yloxy)hexane | HCID 21895501 | — |
| Product | 2-[3-[(6-Bromohexyl)oxy]-1-propynyl]-5-nitropyridine | HCID 19854800 | — |
Reaction Steps
2-Bromo-5-nitropyridine (6.4 g) and 1-bromo-6-[(2-propynyl)oxy]hexane (6.39 g) were treated as in Intermediate 20 to give, after FCC eluting with hexane-ether (2:1), the title compound as a brown oil (7 g), t.l.c. (hexane-ether 5:1) Rf 0.22.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04921867 |
| Source dataset | uspto-grants-1990_05 |
| ORD ID | ord-03c52a5051ff47cb89da48b21c119343 |
| Source note | uspto-grants-1990_05 |