HRID1649960

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6101

4-Methylbenzenesulfonic acid

C7H8O3S

HCID81995

Benzenamine, 4,4'-ethenylidenebis[N,N-dimethyl-

C18H22N2

HCID92742

4,4'-Bis(dimethylamino)benzhydrol

C17H22N2O

PRODUCTS

生成物

结构：CN(C)c1ccc(C(=CC(c2ccc(N(C)C)cc2)c2ccc(N(C)C)cc2)c2ccc(N(C)C)cc2)cc1

HCID19855551

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

Michler's Ethylene (5g) and of 4,4'-bis-(dimethylamino)-benzhydrol (5g, Michler's Hydrol) were dissolved in methanol (50g) and 4-sulphotoluene (0.1g) was added. After stirring and heating under reflux for 2 hours, the insoluble crude product was isolated by filtration, washed with methanol and crystallised from toluene as a white solid (7g), MP 189°-190° C. It has the structure: ##STR12## Use of TDPP as a colour former in a pressure-sensitive copying paper

WORKUP

后处理

temperatureheating
temperatureunder reflux for 2 hours

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-fef92db789bd46b5a752850ac5aa2b05
来源数据集: uspto-grants-1990_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04922020
来源说明: uspto-grants-1990_05

反应 SMILES

[CH3:1][N:2]([C:4]1[CH:9]=[CH:8][C:7]([C:10]([C:12]2[CH:17]=[CH:16][C:15]([N:18]([CH3:20])[CH3:19])=[CH:14][CH:13]=2)=[CH2:11])=[CH:6][CH:5]=1)[CH3:3].[CH3:21][N:22]([CH3:40])[C:23]1[CH:39]=[CH:38][C:26]([CH:27](O)[C:28]2[CH:33]=[CH:32][C:31]([N:34]([CH3:36])[CH3:35])=[CH:30][CH:29]=2)=[CH:25][CH:24]=1.S(C1C=CC(C)=CC=1)(O)(=O)=O>CO>[CH3:20][N:18]([C:15]1[CH:14]=[CH:13][C:12]([C:10]([C:7]2[CH:8]=[CH:9][C:4]([N:2]([CH3:1])[CH3:3])=[CH:5][CH:6]=2)=[CH:11][CH:27]([C:26]2[CH:25]=[CH:24][C:23]([N:22]([CH3:21])[CH3:40])=[CH:39][CH:38]=2)[C:28]2[CH:29]=[CH:30][C:31]([N:34]([CH3:35])[CH3:36])=[CH:32][CH:33]=2)=[CH:17][CH:16]=1)[CH3:19]