Dichloromethane → HCID 14742789, compound

HRID 1651224Notes

Reaction equation

HRID 1651224 reaction equation
[CH2:1]([C:5]1[C:14]2[C:9](=[CH:10][C:11]([O:15][CH3:16])=[CH:12][CH:13]=2)[CH2:8][CH2:7][C:6]=1C=O)[CH2:2][CH2:3][CH3:4].[C:19]([CH:23]=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)([O:21][CH3:22])=[O:20].Cl[CH2:44]Cl>>[CH3:22][O:21][C:19](=[O:20])/[CH:23]=[CH:44]/[C:6]1[CH2:7][CH2:8][C:9]2[C:14](=[CH:13][CH:12]=[C:11]([O:15][CH3:16])[CH:10]=2)[C:5]=1[CH2:1][CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 17453Acetic acid, 2-(triphenylphosphoranylidene)-, methyl esterHCID 14742742HCID 14742742, compound

Product 1

HCID 14742789HCID 14742789, compound

Procedure

As in Example 111, 1-butyl-3,4-dihydro-6-methoxy-2-naphthalenecarboxaldehyde (3.05 g) and (carbomethoxymethylene)triphenylphosphorane (4.5 g) in dichloromethane (25 mL) was stirred at room temperature for 64 hours. The usual work up furnished 2.9 g of (E)-3-(1-butyl-3,4-dihydro-6-methoxy-2-naphthalenyl)-2-propenoic acid methyl ester as an oil.

Sources & evidence

ORD record
ord-fb4a7a85c8364a0d854cec9df8ab56cd
Source dataset
uspto-grants-1990_05
Patent number
US04927838

Reaction notes

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