1-Butanol → HCID 86748625, compound

HRID 1654424Notes

Reaction equation

[CH2:1]([S:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[OH:38][CH2:39][CH:40]([OH:42])[CH3:41].C(O)CCC.[B:48]([OH:51])([OH:50])[OH:49]>C1(C)C=CC=CC=1>[B:48]([OH:51])([OH:50])[OH:49].[CH2:20]([S:19][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37].[OH:38][CH2:39][CH:40]([OH:42])[CH3:41]

Participants

Conditions

Temperature: 60 °C

Procedure

A solution of 1,2-dihydroxypropane octadecyl sulfide (80 g ), prepared as described in Example 1, n-butanol (43 g), and toluene (76 g) was heated to 60° C. and 9.3 g of boric acid were added. The expected amount of water was removed by azeotropic distillation with a maximum reaction temperature of 110° C. The reaction solution was filtered through diatomaceous earth. Solvent was removed by high speed rotary evaporation under reduced pressure yielding a waxy, white solid product.

Workup

customThe expected amount of water was removed by azeotropic distillation with a maximum reaction temperature of 110° C
filtrationThe reaction solution was filtered through diatomaceous earth
customSolvent was removed by high speed rotary evaporation under reduced pressure
customyielding a waxy, white solid product

Sources & evidence

ORD record: ord-9521fe5b28dc4ef8b03cda69d8cbbc90
Source dataset: uspto-grants-1995_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05407451

Reaction notes

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