Diphenyl Ether → HCID 86747261, compound

HRID 1655555Notes

Reaction equation

HRID 1655555 reaction equation
[C:1]1([CH2:7][O:8][C:9]2[CH:10]=[C:11]([NH:23][CH:24]=[C:25]([C:29]([OH:31])=[O:30])[C:26](O)=[O:27])[CH:12]=[CH:13][C:14]=2[O:15][CH2:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:32]1(OC2C=CC=CC=2)C=CC=C[CH:33]=1>C(O)C>[O:27]=[C:26]1[C:12]2[C:11](=[CH:10][C:9]([O:8][CH2:7][C:1]3[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=3)=[C:14]([O:15][CH2:16][C:17]3[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=3)[CH:13]=2)[NH:23][CH:24]=[C:25]1[C:29]([O:31][CH2:32][CH3:33])=[O:30]

Participants

4

Reactant 2

HCID 7583Diphenyl EtherHCID 67849323HCID 67849323, compound

Product 1

HCID 86747261HCID 86747261, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The compound of title 4 (2.55 g, 5.36 mmol) was added under stirring to 21 mL boiling diphenylether. The mixture was heated to reflux for 15 minutes while the resulting ethanol was distilled off. After cooling, ether was added to the resulting suspension. The precipitate (the title compound) was filtered off and dried in vacuo.

Workup

  1. temperatureThe mixture was heated
  2. distillationwas distilled off
  3. temperatureAfter cooling
  4. additionether was added to the resulting suspension
  5. filtrationThe precipitate (the title compound) was filtered off
  6. customdried in vacuo

Sources & evidence

ORD record
ord-617cf8499e6143b9b286adb3ce644b3d
Source dataset
uspto-grants-1993_10
Patent number
US05250691

Reaction notes

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