Hydrogen Peroxide → HCID 13437022, compound

HRID 1658051Notes

Reaction equation

HRID 1658051 reaction equation
[CH3:1][N:2]1[C:11]2[C:6](=[CH:7][CH:8]=[C:9]([C:12]([F:15])([F:14])[F:13])[CH:10]=2)[N:5]=[CH:4][C:3]1=[O:16].[OH:17]O>C(O)(=O)C>[CH3:1][N:2]1[C:11]2[C:6](=[CH:7][CH:8]=[C:9]([C:12]([F:15])([F:13])[F:14])[CH:10]=2)[NH:5][C:4](=[O:17])[C:3]1=[O:16]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 21497066HCID 21497066, compound

Product 1

HCID 13437022HCID 13437022, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

1-Methyl-7-trifluoromethyl-2(1H)-quinoxalinone (2.68 grams) was dissolved in 20 ml. of acetic acid and 20 ml. of 30 percent hydrogen peroxide were added. The reaction mixture was held at room temperature for 24 hours, by which time a solid had separated out. It was collected by filtration. NMR and microanalysis confirmed that the product was 1-methyl-7-trifluoromethyl-2(1H), 3(4H)-quinoxalinedione. The product melted at 283°-287°C.

Workup

  1. customa solid had separated out
  2. filtrationIt was collected by filtration

Sources & evidence

ORD record
ord-09bcc097fa4744b2b177e66aa76595a7
Source dataset
uspto-grants-1976_06
Patent number
US03962440

Reaction notes

Loading…