m-Chloroperbenzoic acid → HCID 12223723, compound

HRID 1658068Notes

Reaction equation

HRID 1658068 reaction equation
[OH:1][CH2:2][CH2:3][N:4]1[C:24](=[O:25])[C:8]2[CH:9]=[CH:10][CH:11]=[C:12]3[S:13][C:14]4[CH:15]=[CH:16][C:17]([C:20]([F:23])([F:22])[F:21])=[CH:18][C:19]=4[N:6]([C:7]=23)[C:5]1=[O:26].ClC1C=CC=C(C(OO)=[O:35])C=1>>[OH:1][CH2:2][CH2:3][N:4]1[C:24](=[O:25])[C:8]2[CH:9]=[CH:10][CH:11]=[C:12]3[S:13](=[O:35])[C:14]4[CH:15]=[CH:16][C:17]([C:20]([F:21])([F:22])[F:23])=[CH:18][C:19]=4[N:6]([C:7]=23)[C:5]1=[O:26]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 122237172-(2-Hydroxyethyl)-10-trifluoromethyl-1H-pyrimido[5,4,3-kl]phenothiazine-1,3(2H)-dione

Product 1

HCID 12223723HCID 12223723, compound

Procedure

When 2-(2-hydroxyethyl)-10-trifluoromethyl-1H-pyrimido[5,4,3-kl]phenothiazine-1,3(2H)-dione was oxidized with m-chloroperbenzoic acid as described in the procedure of Example 6, the title compound was obtained, m.p. 205-206° (ethanol).

Sources & evidence

ORD record
ord-935286508ed349f3bda6debc62a91635
Source dataset
uspto-grants-1976_06
Patent number
US03962438

Reaction notes

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