4-Methoxy-alpha-toluenethiol → HCID 21529156, compound

HRID 1658324Notes

Reaction equation

HRID 1658324 reaction equation
Br[C:2]1[C:3]([C:8]2[O:9][CH2:10][C:11]([CH3:14])([CH3:13])[N:12]=2)=[N:4][CH:5]=[CH:6][CH:7]=1.[Na].[CH3:16][O:17][C:18]1[CH:25]=[CH:24][C:21]([CH2:22][SH:23])=[CH:20][CH:19]=1>>[CH3:13][C:11]1([CH3:14])[CH2:10][O:9][C:8]([C:3]2[C:2]([S:23][CH2:22][C:21]3[CH:24]=[CH:25][C:18]([O:17][CH3:16])=[CH:19][CH:20]=3)=[CH:7][CH:6]=[CH:5][N:4]=2)=[N:12]1

Participants

4

Reactant 3

HCID 804074-Methoxy-alpha-toluenethiolHCID 5360545SodiumHCID 21529153HCID 21529153, compound

Product 1

HCID 21529156HCID 21529156, compound

Procedure

The above prepared 3-bromo-2-(4,4-dimethyl-2-oxazolinyl)pyridine is reacted with the sodium salt of p-methoxybenzyl mercaptan by the procedure of Example 1 to give 2-(4,4-dimethyl-2-oxazolinyl)-3-(p-methoxybenzylthio)pyridine.

Sources & evidence

ORD record
ord-69ec1a39bf4e4a98ab76fcf12c905af1
Source dataset
uspto-grants-1976_06
Patent number
US03963733

Reaction notes

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