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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1658902Generated: October 27, 2026

Hydrogen Bromide → 2-Propenoic acid, 3-phenyl-, methyl ester

https://huagongshe.com/reaction/1658902

Reaction equation

Participants

RoleNameHCIDCharge
ReactantHydrogen BromideHCID 260—
ReactantMethyl AcrylateHCID 7294—
ReactantAllyl AlcoholHCID 7858—
ReactantTriphenylphosphineHCID 11776—
Catalystpalladium(II) acetateHCID 167845—
Product2-Propenoic acid, 3-phenyl-, methyl esterHCID 7644—
ProductMethyl sorbateHCID 5323650—
ProductAllyl sorbateHCID 6435833—

Reaction Conditions

Temperature135 °C

Reaction Steps

Quantities of 5 millimoles palladium acetate, 20 millimoles triphenyl phosphine, 5 millimoles of hydrogen bromide, 600 millimoles allyl alcohol, and 600 millimoles methyl acrylate are introduced into a reaction chamber and heated to 135°C for 20 hours. The final reaction solution produced 15% by weight methyl sorbate, allyl sorbate, and traces of methyl cinnamate.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS03966798
Source datasetuspto-grants-1976_06
ORD IDord-b7841dbc5b3f4c0d944dbee568bac915
Source noteuspto-grants-1976_06