HRID1658902

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID260

Hydrogen Bromide

BrH

HCID7294

Methyl acrylate

C4H6O2

HCID7858

Allyl alcohol

C3H6O

HCID11776

Triphenylphosphine

C18H15P

PRODUCTS

生成物

HCID7644

Methyl cinnamate

C10H10O2

HCID5323650

Methyl (E,E)-sorbate

C7H10O2

HCID6435833

Allyl (2E,4E)-2,4-hexadienoate

C9H12O2

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID167845

Diacetatopalladium

C4H6O4Pd

CONDITIONS

反应条件

温度: 135 °C

PROCEDURE

实验过程

Quantities of 5 millimoles palladium acetate, 20 millimoles triphenyl phosphine, 5 millimoles of hydrogen bromide, 600 millimoles allyl alcohol, and 600 millimoles methyl acrylate are introduced into a reaction chamber and heated to 135°C for 20 hours. The final reaction solution produced 15% by weight methyl sorbate, allyl sorbate, and traces of methyl cinnamate.

WORKUP

后处理

customThe final reaction solution