Diethylamine → HCID 131710374, compound

HRID 1659080Notes

Reaction equation

HRID 1659080 reaction equation
[CH2:1]([NH:3][CH2:4][CH3:5])[CH3:2].[Cl:6][CH:7]([CH2:11][CH2:12][C:13]1[CH:18]=[CH:17][C:16]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=2[Cl:25])=[CH:15][CH:14]=1)[C:8]([OH:10])=[O:9]>CCCCCC>[CH2:1]([NH2+:3][CH2:4][CH3:5])[CH3:2].[Cl:6][CH:7]([CH2:11][CH2:12][C:13]1[CH:18]=[CH:17][C:16]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=2[Cl:25])=[CH:15][CH:14]=1)[C:8]([O-:10])=[O:9]

Participants

4

Reactant 2

HCID 8021DiethylamineHCID 21525974HCID 21525974, compound

Product 1

HCID 131710374HCID 131710374, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Anhydrous diethylamine (0.11 moles) is added dropwise to a stirred solution of α-chloro-γ-(2'-chloro-4-biphenylyl)butyric acid (0.10 moles) in 100 ml. of n-hexane at 0°C. The precipitate is collected on a filter, washed with n-hexane, and dried in a vacuum desiccator to obtain α-chloro-γ-(2'-chloro-4-biphenylyl)butyric acid, diethylammonium salt.

Workup

  1. customat 0°C
  2. customThe precipitate is collected on a filter
  3. washwashed with n-hexane
  4. customdried in a vacuum desiccator

Sources & evidence

ORD record
ord-300c995253a94fc8aa0ab0997715898e
Source dataset
uspto-grants-1976_06
Patent number
US03966801

Reaction notes

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