Water → HCID 20559067, compound

HRID 1659446Notes

Reaction equation

HRID 1659446 reaction equation
CS[S:3][CH3:4].[CH3:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].O.[CH2:12]([O:14]CC)[CH3:13].C(#[N:19])C>>[C:12]([NH:19][CH:6]([CH2:7][CH2:8][CH2:9][CH3:10])[CH2:5][S:3][CH3:4])(=[O:14])[CH3:13]

Participants

6

Reactant 5

HCID 962WaterHCID 3283Diethyl EtherHCID 6342AcetonitrileHCID 8058HexaneHCID 12232Dimethyl Disulfide

Product 1

HCID 20559067HCID 20559067, compound

Procedure

The procedure of Example 1 was repeated using dimethyldisulphide (96 mg; 1.02 mmol) and 1-hexane (670 mg: 8 mmol) in acetonitrile (15 ml) at +1.20 V until 1.3 coulomb equivalents of charge had been passed. After the addition of water and extraction with diethyl ether there was obtained 36 mg of 2-acetamido-1-methylthio-hexane. Mass Spec. m/e 189 (M+), 130 (57%) and 86 (100%). I.R. 3290 & 1645 cm-1.

Workup

  1. additionof charge

Sources & evidence

ORD record
ord-780a856c27ae40c99c4ce456bd885a42
Source dataset
uspto-grants-1981_12
Patent number
US04304642

Reaction notes

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