m-Chloroperbenzoic acid → HCID 15578429, compound

HRID 1659503Notes

Reaction equation

HRID 1659503 reaction equation
[Br:1][C:2]1[C:7](=[O:8])[CH:6]=[C:5]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[O:4][C:3]=1[C:15]([O:17][CH2:18][S:19][CH3:20])=[O:16].ClC1C=C(C=CC=1)C(OO)=[O:26]>C(Cl)(Cl)Cl>[Br:1][C:2]1[C:7](=[O:8])[CH:6]=[C:5]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[O:4][C:3]=1[C:15]([O:17][CH2:18][S:19]([CH3:20])=[O:26])=[O:16]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 15578428HCID 15578428, compound

Product 1

HCID 15578429HCID 15578429, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A solution of methylthiomethyl 3-bromo-4-oxo-6-phenyl-4H-pyran-2-carboxylate (0.36 g) and m-chloroperoxybenzoic acid (0.22 g, 80% pure) in chloroform (5 ml) was stirred for 4 hours at room temperature, filtered, washed with sodium bicarbonate solution, and evaporated. The residue was recrystallised from ethyl acetate-petroleum ether 60°-80° C. to give the title product (mp 159° C.).

Workup

  1. filtrationfiltered
  2. washwashed with sodium bicarbonate solution
  3. customevaporated
  4. customThe residue was recrystallised from ethyl acetate-petroleum ether 60°-80° C.

Sources & evidence

ORD record
ord-88188dcf39c34faa96fd02251aa5b2fb
Source dataset
uspto-grants-1981_12
Patent number
US04304728

Reaction notes

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