Trichloromethanesulfenyl chloride → HCID 20519650, compound
Reaction equation
[Cl:1][C:2]([Cl:6])([Cl:5])[S:3]Cl.[Na].[C:8]([C:10]1[C:11](=[O:25])[NH:12][C:13](=[O:24])[N:14]([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=2[CH2:22][CH3:23])[CH:15]=1)#[N:9].[C:26]([C:28]1[C:29](=[O:45])[NH:30][C:31](=[O:44])[N:32]([C:34]2[C:39]([CH2:40][CH3:41])=[CH:38][CH:37]=[CH:36][C:35]=2[CH2:42][CH3:43])[CH:33]=1)#[N:27].[C:46]([C:48]1[C:49](=[O:64])[NH:50][C:51](=[O:63])[N:52]([C:54]2[CH:59]=[CH:58][CH:57]=[CH:56][C:55]=2[CH:60]([CH3:62])[CH3:61])[CH:53]=1)#[N:47]>>[C:8]([C:10]1[C:11](=[O:25])[N:12]([S:3][C:2]([Cl:6])([Cl:5])[Cl:1])[C:13](=[O:24])[N:14]([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=2[CH2:22][CH3:23])[CH:15]=1)#[N:9].[C:26]([C:28]1[C:29](=[O:45])[N:30]([S:3][C:2]([Cl:6])([Cl:5])[Cl:1])[C:31](=[O:44])[N:32]([C:34]2[C:39]([CH2:40][CH3:41])=[CH:38][CH:37]=[CH:36][C:35]=2[CH2:42][CH3:43])[CH:33]=1)#[N:27].[C:46]([C:48]1[C:49](=[O:64])[N:50]([S:3][C:2]([Cl:6])([Cl:5])[Cl:1])[C:51](=[O:63])[N:52]([C:54]2[CH:59]=[CH:58][CH:57]=[CH:56][C:55]=2[CH:60]([CH3:61])[CH3:62])[CH:53]=1)#[N:47]Participants
8
Procedure
Following the procedure of Example 1, trichloromethanesulphenyl chloride is reacted with the sodium salt of each of 5-cyano-1-(2-ethylphenyl)uracil, 5-cyano-1-(2,6-diethylphenyl)uracil and 5-cyano-1-(2-isopropylphenyl)uracil to yield 5-cyano-1-(2-ethylphenyl)-3-trichloromethanesulphenyluracil, 5-cyano-1-(2,6-diethylphenyl)-3-trichloromethanesulphenyluracil and 5-cyano-1-(2-isopropylphenyl)-3-trichloromethanesulphenyluracil.
Sources & evidence
- ORD record
- ord-187f2f5b889d46c0a87fd0a58b40e534
- Source dataset
- uspto-grants-1981_12
- Patent number
- US04307098
Reaction notes
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