Sodium → HCID 20519687, compound

HRID 1660172Notes

Reaction equation

HRID 1660172 reaction equation
[Na].[C:2]([C:4]1[C:5](=[O:19])[NH:6][C:7](=[O:18])[N:8]([C:10]2[C:15]([CH3:16])=[CH:14][CH:13]=[CH:12][C:11]=2[CH3:17])[CH:9]=1)#[N:3].[Br:20][C:21]([Cl:27])([S:25]Cl)[CH:22]([Br:24])[Cl:23].[Cl:28][C:29]([Cl:36])([S:34]Cl)[C:30]([Cl:33])([Cl:32])[Cl:31]>>[C:2]([C:4]1[C:5](=[O:19])[N:6]([S:25][C:21]([Br:20])([Cl:27])[CH:22]([Br:24])[Cl:23])[C:7](=[O:18])[N:8]([C:10]2[C:15]([CH3:16])=[CH:14][CH:13]=[CH:12][C:11]=2[CH3:17])[CH:9]=1)#[N:3].[C:2]([C:4]1[C:5](=[O:19])[N:6]([S:34][C:29]([Cl:36])([Cl:28])[C:30]([Cl:33])([Cl:32])[Cl:31])[C:7](=[O:18])[N:8]([C:10]2[C:15]([CH3:16])=[CH:14][CH:13]=[CH:12][C:11]=2[CH3:17])[CH:9]=1)#[N:3]

Participants

6

Reactant 4

HCID 5360545SodiumHCID 13014421HCID 13014421, compoundHCID 13510338HCID 13510338, compoundHCID 20519677HCID 20519677, compound

Product 2

HCID 20519687HCID 20519687, compoundHCID 20519711HCID 20519711, compound

Procedure

The sodium salt of 5-cyano-1-(2,6-dimethylphenyl)uracil is reacted with each of 1,2-dibromo-1,2-dichloroethanesulphenyl chloride and pentachloroethanesulphenyl chloride to yield 5-cyano-1-(2,6-dimethylphenyl)-3-(1,2-dibromo-1,2-dichloroethanesulphenyl)uracil and 5-cyano-1-(2,6-dimethylphenyl)-3-pentachloroethanesulphenyluracil.

Sources & evidence

ORD record
ord-56ea21f006704fce95d5a562db79f82f
Source dataset
uspto-grants-1981_12
Patent number
US04307098

Reaction notes

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