Dichloromethane → HCID 131712261, compound

HRID 1660570Notes

Reaction equation

[CH3:1][C:2]1[CH:7]([CH2:8][CH2:9][C:10]([CH3:12])=O)[C:6]([CH3:14])([CH3:13])[CH2:5][CH2:4]C=1.Cl[OH:16].CCCCCC.[CH2:23]([Cl:25])Cl>>[Cl:25][CH:23]1[C:2](=[CH2:1])[CH:7]([CH2:8][C:9](=[O:16])[CH2:10][CH3:12])[C:6]([CH3:14])([CH3:13])[CH2:5][CH2:4]1

Participants

Reactant 4

HCID 6344Dichloromethane

HCID 8058Hexane

HCID 24341Hypochlorous Acid

HCID 35821Dihydro-alpha-ionone

Product 1

HCID 131712261HCID 131712261, compoundYield 59%

Procedure

The reaction of α-dihydro-ionone and hypochlorous acid was carried out as described in Example 1 except that hexane was substituted for methylene chloride. A 59% yield of 4-(5-chloro-6-methylene-2,2-dimethylcyclohexyl-2-butanone was obtained. The spectral data was identical to that reported in Example 1.

Sources & evidence

ORD record: ord-116bf892051c412385583456dc846fa6
Source dataset: uspto-grants-1981_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04308401

Reaction notes

Loading…