m-Chloroperbenzoic acid → HCID 59609585, compound

HRID 1660674Notes

Reaction equation

HRID 1660674 reaction equation
[CH3:1][N:2]1[C:15]2[CH:14]=[CH:13][C:12]([C:16]3[C:25]4[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=4)[CH:19]=[CH:18][CH:17]=3)=[CH:11][C:10]=2[S:9](=[O:26])[C:8]2[C:3]1=[CH:4][CH:5]=[C:6]([C:27]1[C:36]3[C:31](=[CH:32][CH:33]=[CH:34][CH:35]=3)[CH:30]=[CH:29][CH:28]=1)[CH:7]=2.ClC1C=CC=C(C(OO)=[O:45])C=1>>[CH3:1][N:2]1[C:15]2[CH:14]=[CH:13][C:12]([C:16]3[C:25]4[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=4)[CH:19]=[CH:18][CH:17]=3)=[CH:11][C:10]=2[S:9](=[O:45])(=[O:26])[C:8]2[C:3]1=[CH:4][CH:5]=[C:6]([C:27]1[C:36]3[C:31](=[CH:32][CH:33]=[CH:34][CH:35]=3)[CH:30]=[CH:29][CH:28]=1)[CH:7]=2

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 59609623HCID 59609623, compound

Product 1

HCID 59609585HCID 59609585, compound

Procedure

For the preparation as a by-product in the synthesis of 10-methyl-3,7-bis(1-naphthyl)phenothiazine 5-oxide, see under Example 5. For a selective preparation of the sulfone, at least two molar equivalents of m-chloroperbenzoic acid are used.

Workup

  1. customFor the preparation as a by-product

Sources & evidence

ORD record
ord-2b83896897a3434c9ae4badf2eb8a0e4
Source dataset
uspto-grants-2011_10
Patent number
US08029919B2

Reaction notes

Loading…