m-Chloroperbenzoic acid → HCID 59609603, compound

HRID 1660676Notes

Reaction equation

HRID 1660676 reaction equation
[CH3:1][N:2]1[C:15]2[CH:14]=[CH:13][C:12]([C:16]3[CH:25]=[CH:24][C:23]4[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=4)[CH:17]=3)=[CH:11][C:10]=2[S:9](=[O:26])[C:8]2[C:3]1=[CH:4][CH:5]=[C:6]([C:27]1[CH:36]=[CH:35][C:34]3[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=3)[CH:28]=1)[CH:7]=2.ClC1C=CC=C(C(OO)=[O:45])C=1>>[CH3:1][N:2]1[C:3]2[CH:4]=[CH:5][C:6]([C:27]3[CH:36]=[CH:35][C:34]4[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=4)[CH:28]=3)=[CH:7][C:8]=2[S:9](=[O:45])(=[O:26])[C:10]2[C:15]1=[CH:14][CH:13]=[C:12]([C:16]1[CH:25]=[CH:24][C:23]3[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=3)[CH:17]=1)[CH:11]=2

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 59609637HCID 59609637, compound

Product 1

HCID 59609603HCID 59609603, compound

Procedure

For the preparation as a by-product in the synthesis of 10-methyl-3,7-bis(2-naphthyl)phenothiazine 5-oxide, see under Example 8. For a selective preparation of the sulfone, at least two molar equivalents of m-chloroperbenzoic acid are used. Yellowish microcrystals having a melting point of 328-332° C. were obtained.

Workup

  1. customFor the preparation as a by-product
  2. customwere obtained

Sources & evidence

ORD record
ord-2cce0eb6c5ba48c08bc7e0f8d9fcbd5f
Source dataset
uspto-grants-2011_10
Patent number
US08029919B2

Reaction notes

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