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HRID1661854

反应详情

EQUATION

反应方程式

HRID 1661854 的结构方程式

REACTANTS

反应物

2
结构：C=CCOCC(CC)(CO)COCC=C
HCID61196

2,2-Bis[(prop-2-en-1-yloxy)methyl]butan-1-ol

C12H22O3

结构：CC(C[PH](=O)O)CC(C)(C)C
HCID178460681

未命名化合物

PRODUCTS

生成物

1
结构：CCC(CO)(COCCCP(=O)(O)CC(C)CC(C)(C)C)COCCCP(=O)(O)CC(C)CC(C)(C)C
HCID57909086

未命名化合物

收率 100.1%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCC(C)(C)OOC(C)(C)CC
催化剂HCID25320

Bis(2-methylbutan-2-yl) peroxide

C10H22O2

CONDITIONS

反应条件

温度
140 °C

PROCEDURE

实验过程

10 g (0.056 moles) of 2,4,4-trimethylpentyl phosphinic acid, 6.01 g (0.028 moles) of trimethylolpropane diallyl ether and 0.4 mL (0.0019 moles) of di-tert-amylperoxide are mixed in a 100 mL single neck flask. The mixture is purged with argon to remove oxygen and is heated under argon for 6 hours at 140° C. Tert-amyl alcohol is removed by distillation and 16 g (quantitative yield) of [3-(2-hydroxymethyl-2-{3-[hydroxy-(2,4,4-trimethylpentyl)-phosphinoyl]-propoxymethyl}-butoxy)-propyl]-(2,4,4-trimethylpentyl)-phosphinic acid is obtained as a viscous oil.

WORKUP

后处理

  1. customThe mixture is purged with argon
  2. customto remove oxygen
  3. customTert-amyl alcohol is removed by distillation