Water → HCID 86608401, compound

HRID 1662164Notes

Reaction equation

HRID 1662164 reaction equation
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[S:9]([O:14]C)([O:12][CH3:13])(=[O:11])=[O:10].O>C(OCC)C>[S:9]([O-:14])([OH:12])(=[O:11])=[O:10].[CH3:8][S+:7]([CH3:13])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 962WaterHCID 6497Dimethyl SulfateHCID 7520Thioanisole

Product 1

HCID 86608401HCID 86608401, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

6.2 g (0.05 mole) of thioanisole and 6.9 g (0.055 mole) of dimethyl sulfate were stirred for 12 hours at room temperature. 100 g of water and 50 ml of diethyl ether were added to the reaction solution whereupon the mixture separated into two layers. The aqueous layer was taken out, which was an aqueous solution of the target compound, dimethylphenylsulfonium hydrogen sulfate.

Workup

  1. customseparated into two layers

Sources & evidence

ORD record
ord-b3901ea4b14040549059ba840a94a1ce
Source dataset
uspto-grants-2011_10
Patent number
US08030515B2

Reaction notes

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