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HRID1662556

反应详情

EQUATION

反应方程式

HRID 1662556 的结构方程式

REACTANTS

反应物

3
结构：CC(C)=C1C(=O)OC(C)(C)OC1=O
HCID75218

2,2-Dimethyl-5-(1-methylethylidene)-1,3-dioxane-4,6-dione

C9H12O4

结构：COc1cccc(-c2ccc(COc3cccc(CCC(=O)O)c3)cc2C)c1
HCID25261298

Benzenepropanoic acid, 3-[(3′-methoxy-2-methyl[1,1′-biphenyl]-4-yl)methoxy]-

C24H24O4

结构：COc1cccc([Mg]Br)c1
HCID178490745

未命名化合物

PRODUCTS

生成物

1
结构：COc1cccc(C(C)(C)C2C(=O)OC(C)(C)OC2=O)c1
HCID57707254

未命名化合物

PROCEDURE

实验过程

The 5-(2-(3-methoxyphenyl)propan-2-yl)-2,2-dimethyl-1,3-dioxane-4,6-dione (85.C) was prepared via the procedure described in Huang, X.; et. al.; Tetrahedron Letters; 1982, (1); pp. 75-76. from (3-methoxyphenyl)magnesium bromide (1.0 M in THF solution from Aldrich) and 85.B. 1H NMR (400 MHz, CDCl3) ppm 7.26 (1H, t, J=8.0 Hz), 6.94 (1H, d, J=7.8 Hz), 6.89 (1H, t, J=2.2 Hz), 6.79 (1H, dd, J=8.2, 2.3 Hz), 3.81 (3H, s), 3.62 (1H, s), 1.67 (6H, s), 1.66 (3H, s), 1.34 (3H, s).