Tempo → (E)-1-(3-(Benzyloxy)phenyl)but-2-en-1-one

HRID 1662569Notes

Reaction equation

HRID 1662569 reaction equation
[CH2:1]([O:8][C:9]1[CH:10]=[C:11]([CH:15]([OH:19])/[CH:16]=[CH:17]/[CH3:18])[CH:12]=[CH:13][CH:14]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.CC1(C)N([O])C(C)(C)CCC1.C(O)(=O)C.C(O)(=O)C.IC1C=CC=CC=1>>[CH2:1]([O:8][C:9]1[CH:10]=[C:11]([C:15](=[O:19])/[CH:16]=[CH:17]/[CH3:18])[CH:12]=[CH:13][CH:14]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 3

HCID 2724126TempoHCID 12217721Iodo benzene diacetateHCID 57707124(E)-1-(3-(Benzyloxy)phenyl)but-2-en-1-ol

Product 1

HCID 57706211(E)-1-(3-(Benzyloxy)phenyl)but-2-en-1-one

Procedure

93.C was prepared from 93.B via oxidation with TEMPO and iodobenzene diacetate according to the analogous method described in Example 90.

Sources & evidence

ORD record
ord-01771bad06914b56804b1e2a58b95f0d
Source dataset
uspto-grants-2011_10
Patent number
US08030354B2

Reaction notes

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