1-Chloromethylnaphthalene → O-(naphthalen-1-ylmethyl)hydroxylamine

HRID 1663112Notes

Reaction equation

HRID 1663112 reaction equation
[OH:1][N:2]1C(=O)C2=CC=CC=C2C1=O.Cl[CH2:14][C:15]1[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[CH:18]=[CH:17][CH:16]=1>>[C:15]1([CH2:14][O:1][NH2:2])[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[CH:18]=[CH:17][CH:16]=1

Participants

3

Reactant 2

HCID 68451-ChloromethylnaphthaleneHCID 10665N-Hydroxyphthalimide

Product 1

HCID 15009996O-(naphthalen-1-ylmethyl)hydroxylamine

Procedure

Prepared by a similar procedure as described for preparation 13. Starting materials: N-Hydroxyphthalimide and 1-chloromethyl-naphthalen. 13C-NMR (DMSO-d6) δ 133.5, 133.2, 131.4, 128.2, 126.8, 126.7, 126.0, 125.6, 125.2, 124.1, 75.4.

Workup

  1. customPrepared by a similar procedure
  2. customas described for preparation 13

Sources & evidence

ORD record
ord-bca39f7810714098a080e87e71027dca
Source dataset
uspto-grants-2011_10
Patent number
US08034811B2

Reaction notes

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