HuagongsheHuagongshe Chemistry Print Report · For research reference only
Lithium Carbonate → HCID 86625161, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Lithium Carbonate | HCID 11125 | — |
| Reactant | 3-Methoxybenzyl chloride | HCID 69994 | — |
| Reactant | 5-Bromo-3,4-dihydroxybenzaldehyde | HCID 85405 | — |
| Catalyst | Tetrabutylammonium Iodide | HCID 67553 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 86625161 | HCID 86625161 | — |
Reaction Steps
A mixture of 3-bromo-4,5-dihydroxy-benzaldehyde (1 g), lithium carbonate (314 mg), 3-methoxybenzyl chloride (742 μl) and a catalytic amount of tetrabutylammonium iodide in DMF (5 ml) was stirred at 60° C. for 17 h. The mixture was diluted with ethyl acetate and washed with water. The organic layer was dried (MgSO4), filtered and concentrated in vacuo.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08034945B2 |
| Source dataset | uspto-grants-2011_10 |
| ORD ID | ord-6c2e2a4cff604669adff8b56816eea98 |
| Source note | uspto-grants-2011_10 |