Ammonium thiocyanate → HCID 86639443, compound

HRID 1666776Notes

Reaction equation

HRID 1666776 reaction equation
[S-:1][C:2]#[N:3].[NH4+].[N:5]12[CH2:15][CH2:14][CH2:13][N:12]=[C:11]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]2>>[S-:1][C:2]#[N:3].[NH+:5]12[CH2:15][CH2:14][CH2:13][N:12]=[C:11]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]2

Participants

3

Reactant 2

HCID 15666Ammonium thiocyanateHCID 811841,8-Diazabicyclo(5.4.0)undec-7-ene

Product 1

HCID 86639443HCID 86639443, compound

Procedure

38.1 g (0.5 mol) of ammonium thiocyanate were introduced into a 500 ml stirred reactor fitted with nitrogen inlet and separate feed device and suspended in 200 ml of methanol. Over the course of 30 minutes 76.1 g (0.5 mol) of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) were added, where upon the reaction mixture was solubilized. The mixture was stirred for a further three hours and then the solvent was evaporated and the remaining solid dried in vacuo.

Workup

  1. customfitted with nitrogen inlet
  2. customseparate feed device
  3. stirringThe mixture was stirred for a further three hours
  4. customthe solvent was evaporated
  5. customthe remaining solid dried in vacuo

Sources & evidence

ORD record
ord-b3ed8177d6f44876a2a5155ad887ee49
Source dataset
uspto-grants-2011_10
Patent number
US08044120B2

Reaction notes

Loading…