1-Bromo-3-methylbutane → Isopentadecan-1-ol

HRID 1670377Notes

Reaction equation

HRID 1670377 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][OH:12].[CH3:13][CH:14]([CH3:18])[CH2:15][CH2:16]Br>>[CH3:13][CH:14]([CH3:18])[CH2:15][CH2:16][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][OH:12]

Participants

3

Reactant 2

HCID 78911-Bromo-3-methylbutaneHCID 1045071-Decanol, 10-bromo-

Product 1

HCID 94094Isopentadecan-1-olYield 62%

Procedure

13-methyltetradecan-1-ol was prepared from 10-bromodecanol and 3-methylbutylbromide in 62% yield. The 1H NMR and MS-ESI data matched those reported by Yuasa et al. (Yuasa and Tsuruta (2004) Flavour and Fragrance Journal 19:199-204).

Sources & evidence

ORD record
ord-739e74c236e94a4c8d44ebfd30a74ead
Source dataset
uspto-grants-2011_08
Patent number
US07994143B2

Reaction notes

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