1-Nonanol, 9-bromo- → 14-Methyl-1-pentadecanol

HRID 1670378Notes

Reaction equation

HRID 1670378 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][OH:11].[CH3:12][CH:13]([CH3:19])[CH2:14][CH2:15][CH2:16][CH2:17]Br>>[CH3:12][CH:13]([CH3:19])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][OH:11]

Participants

3

Reactant 2

HCID 1087001-Nonanol, 9-bromo-HCID 5207261-Bromo-5-methylhexane

Product 1

HCID 528326514-Methyl-1-pentadecanolYield 55%

Procedure

14-methylpentadecan-1-ol was prepared from 9-bromononanol and 5-methylhexylbromide in 55% yield. The 1H NMR and MS-ESI data matched those reported by Yuasa et al. (Yuasa and Tsuruta (2004) Flavour and Fragrance Journal 19:199-204).

Sources & evidence

ORD record
ord-85af44fe06d44b07baca65b45c22147f
Source dataset
uspto-grants-2011_08
Patent number
US07994143B2

Reaction notes

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