HCID 178448029, compound → HCID 178455757, compound

HRID 1673166Notes

Reaction equation

HRID 1673166 reaction equation
[CH2:1]([C@H:4]1[CH2:9][CH2:8][C@H:7]([C@H:10]2[CH2:15][CH2:14][C@H:13]([CH:16]3O[C:18](=O)[CH2:17]3)[CH2:12][CH2:11]2)[CH2:6][CH2:5]1)[CH2:2]C>CCCCCCC>[CH:1]([C@H:4]1[CH2:9][CH2:8][C@H:7]([C@H:10]2[CH2:15][CH2:14][C@H:13]([CH2:16][CH2:17][CH3:18])[CH2:12][CH2:11]2)[CH2:6][CH2:5]1)=[CH2:2]

Participants

3

Reactant 1

HCID 178448029HCID 178448029, compound

Product 1

HCID 178455757HCID 178455757, compoundYield 967.7%

Reagents, catalysts & solvents 1

HCID 8900HeptaneSolvent

Conditions

Temperature
170 °C

Procedure

4-(trans-4-(trans-4-Propylcyclohexyl)cyclohexyl)-2-oxetanone (1 g, 3.1 mmol) obtained in Example 2 was placed in a reactor, the interior of which was then sufficiently replaced by nitrogen. The reactor was heated, and after heating to 170° C. for 3 hours, it was cooled to room temperature. The resulting solid was dissolved in heptane and purified with silica gel chromatography to provide trans-1-ethenyl-4-(trans-4-propyl-cyclohexyl)cyclohexane (0.83 g, 30 mmol, yield: 95%).

Workup

  1. temperatureThe reactor was heated
  2. temperatureit was cooled to room temperature
  3. custompurified with silica gel chromatography

Sources & evidence

ORD record
ord-93e4ad85255941e7aab8567d777f5bb7
Source dataset
uspto-grants-2011_08
Patent number
US07999123B2

Reaction notes

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