HCID 178444496, compound → HCID 178455759, compound

HRID 1673168Notes

Reaction equation

[CH2:1]([C@H:6]1[CH2:11][CH2:10][C@H:9]([C@H:12]2[CH2:17][CH2:16][C@H:15]([CH:18]3OC(=O)[CH2:19]3)[CH2:14][CH2:13]2)[CH2:8][CH2:7]1)[CH2:2][CH2:3][CH2:4][CH3:5]>CCCCCCC>[CH:18]([C@H:15]1[CH2:16][CH2:17][C@H:12]([C@H:9]2[CH2:10][CH2:11][C@H:6]([CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])[CH2:7][CH2:8]2)[CH2:13][CH2:14]1)=[CH2:19]

Participants

Conditions

Temperature: 170 °C

Procedure

4-(trans-4-(trans-4-pentylcyclohexyl)cyclohexyl) -2-oxetanone obtained in Example 5 was placed in a reactor, the interior of which was then sufficiently replaced by nitrogen. The reactor was heated, and after heating to 170° C. for 3 hours, it was cooled to room temperature. The resulting solid was dissolved in heptane and purified with silica gel chromatography to provide trans-1-ethenyl -4-(trans-4-pentylcyclohexyl)-cyclohexane at a yield of 95%.

Workup

temperatureThe reactor was heated
temperatureit was cooled to room temperature
custompurified with silica gel chromatography

Sources & evidence

ORD record: ord-0f15dab5cf804524903496ab5745b8c8
Source dataset: uspto-grants-2011_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07999123B2

Reaction notes

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