3-Aminophenol → 6-ethyl-N,N'-bis(3-hydroxyphenyl)-1,3,5-triazine-2,4-diamine

HRID 1674505Notes

Reaction equation

HRID 1674505 reaction equation
[NH2:1][C:2]1[CH:3]=[C:4]([OH:8])[CH:5]=[CH:6][CH:7]=1.Cl[C:10]1[N:15]=[C:14](Cl)[N:13]=[C:12]([CH2:17][CH3:18])[N:11]=1>O1CCOCC1>[CH2:17]([C:12]1[N:13]=[C:14]([NH:1][C:2]2[CH:7]=[CH:6][CH:5]=[C:4]([OH:8])[CH:3]=2)[N:15]=[C:10]([NH:1][C:2]2[CH:7]=[CH:6][CH:5]=[C:4]([OH:8])[CH:3]=2)[N:11]=1)[CH3:18]

Participants

4

Reactant 2

HCID 115683-AminophenolHCID 127762,4-dichloro-6-ethyl-1,3,5-triazine

Product 1

HCID 98583796-ethyl-N,N'-bis(3-hydroxyphenyl)-1,3,5-triazine-2,4-diamine

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

After dissolving 3-aminophenol (2.18 g, 20 mmol) in 1,4-dioxane (20.0 mL), 2,4-dichloro-6-ethyl-1,3,5-triazine (1.78 g, 10 mmol) was added and stirring carried out for 3 hours at 100° C. under a nitrogen atmosphere.

Workup

  1. additionwas added

Sources & evidence

ORD record
ord-0a8da5e126084112bde0de5c025ceca9
Source dataset
uspto-grants-2011_08
Patent number
US08003645B2

Reaction notes

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