Sodium Azide → HCID 17966438, compound

HRID 1675798Notes

Reaction equation

HRID 1675798 reaction equation
[N-:1]=[N+:2]=[N-:3].[Na+].Br[C:6]1[CH:11]=[CH:10][N:9]=[C:8]([C:12]#[N:13])[C:7]=1[O:14][CH3:15]>CN(C)C=O>[N:1]([C:6]1[CH:11]=[CH:10][N:9]=[C:8]([C:12]#[N:13])[C:7]=1[O:14][CH3:15])=[N+:2]=[N-:3]

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 17966439HCID 17966439, compound

Product 1

HCID 17966438HCID 17966438, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent2×

Procedure

To 1 g (0.0155 moles) of sodium azide in 25 mL of dimethylformamide at 0° C., there is added gently 3 g (0.0141 moles) of 4-bromo-2-cyano-3-methoxypyridine from Example b), dissolved in 40 mL of dimethylformamide.

Sources & evidence

ORD record
ord-1a23a4d6a2774f8db0b46315b7b03c55
Source dataset
uspto-grants-2011_08
Patent number
US08003799B2

Reaction notes

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