HRID1677122

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8058

n-Hexane

C6H14

结构：CCOC(=O)C(=CNc1ccccc1C(F)(F)F)C(=O)c1ccccc1

HCID178471912

未命名化合物

PRODUCTS

生成物

结构：O=C(c1ccccc1)c1cnc2c(C(F)(F)F)cccc2c1O

HCID178519486

未命名化合物

收率 64%

AUXILIARIES

试剂、催化剂与溶剂

结构：c1ccc(-c2ccccc2)cc1.c1ccc(Oc2ccccc2)cc1

溶剂HCID24670

Phenyl ether-biphenyl mixture

C24H20O

PROCEDURE

实验过程

A solution of ethyl 2-benzoyl-3-[2-(trifluoromethyl)phenylamino]acrylate (30.5 g, 84.0 mmol) in Dowtherm® (280 mL) was stirred at 260° C. for 11 hours. The reaction solution was returned to room temperature, then added with hexane and recrystallized. The title compound (17.0 g, yield 64%) was obtained as a brown oil.

WORKUP

后处理

customwas returned to room temperature
customrecrystallized