N-Methylbutylamine → HCID 20364374, compound

HRID 1678841Notes

Reaction equation

HRID 1678841 reaction equation
[CH3:1][NH:2][CH2:3][CH2:4][CH2:5][CH3:6].[C:7]([O:11][CH2:12][CH3:13])(=[O:10])[CH:8]=[CH2:9]>>[CH3:1][N:2]([CH2:3][CH2:4][CH2:5][CH3:6])[CH2:9][CH2:8][C:7]([O:11][CH2:12][CH3:13])=[O:10]

Participants

3

Reactant 2

HCID 8068N-MethylbutylamineHCID 8821Ethyl Acrylate

Product 1

HCID 20364374HCID 20364374, compoundYield 87.2%

Procedure

A stirred mixture of N-methyl-n-butylamine (42.8 g., 0.49 mole) and ethyl acrylate (55 g., 0.54 mole) was heated at 80°-90° C for 20 hours. Excess acrylate was evaporated under reduced pressure, and the residue distilled to give 80.0 g (87%) of the title compound, b.p. 97° C at 12 mm.

Workup

  1. temperaturewas heated at 80°-90° C for 20 hours
  2. customExcess acrylate was evaporated under reduced pressure
  3. distillationthe residue distilled

Sources & evidence

ORD record
ord-29fb706d76f741a8a81cee68d6e4b6de
Source dataset
uspto-grants-1978_03
Patent number
US04077941

Reaction notes

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