Aluminum isopropoxide → 1,1-Dichloro-4-methylpent-1-en-3-ol

HRID 1679641Notes

Reaction equation

HRID 1679641 reaction equation

[Cl:1][C:2]([Cl:9])=[CH:3][C:4](=[O:8])[CH:5]([CH3:7])[CH3:6].CC(C)[O-].[Al+3].CC(C)[O-].CC(C)[O-]>C(O)(C)C>[Cl:1][C:2]([Cl:9])=[CH:3][CH:4]([OH:8])[CH:5]([CH3:7])[CH3:6]

Participants

4

Reactant 2

HCID 11143Aluminum isopropoxide

HCID 12286065HCID 12286065, compound

Product 1

HCID 130402971,1-Dichloro-4-methylpent-1-en-3-ol

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

reducing said 1,1-dichloro-4-methyl-1-penten-3-one with aluminum isopropoxide and isopropanol to produce 1,1-dichloro-3-hydroxy-4-methyl-1-pentene,

Sources & evidence

ORD record: ord-61c99ca2bad54e34bc46f327715bcb06
Source dataset: uspto-grants-1978_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04081488

Reaction notes

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