2,5-Pyridinedicarboxylic acid → 2,6-Pyridinedimethanol

HRID 1680525Notes

Reaction equation

HRID 1680525 reaction equation
[N:1]1[CH:6]=[C:5](C(O)=O)[CH:4]=[CH:3][C:2]=1[C:10]([OH:12])=O.[CH3:13][O:14]C1C=C(C=C(OC)C=1OC)C(O)=O>>[N:1]1[C:2]([CH2:10][OH:12])=[CH:3][CH:4]=[CH:5][C:6]=1[CH2:13][OH:14]

Participants

3

Reactant 2

HCID 74932,5-Pyridinedicarboxylic acidHCID 83573,4,5-Trimethoxybenzoic Acid

Product 1

HCID 709572,6-Pyridinedimethanol

Procedure

Pyridine 2,5-dicarboxylic acid is reacted in a process similar to that utilized in the reaction of 3,4,5-trimethoxybenzoic acid set forth in the first two portions of the procedure of Example I so as to produce the corresponding mixed anhydride that is subjected to the catalytic hydrogatation to obtain pyridine 2,6-dimethanol.

Workup

  1. customto produce the

Sources & evidence

ORD record
ord-c1b9f7558fbb413a8a48a3eeec289c29
Source dataset
uspto-grants-1981_06
Patent number
US04273931

Reaction notes

Loading…