HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloroform → HCID 13020713, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloroform | HCID 6212 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Reactant | HCID 86737816 | HCID 86737816 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Solvent | Chloroform hexane | HCID 21585165 | — |
| Product | HCID 13020713 | HCID 13020713 | — |
Reaction Steps
A mixture of AlCl3 (8.0 g, 60 mmole) and LiAlH4 (6.8 g, 180 mmole) was prepared in Et2O (600 ml) as described above. To this was added 5c (21.3 g, 60 mmole) in Et2O (1 L) and the mixture refluxed for 36 hours. Processing as described gave a foam. Crystals of 6c (10.0 g) as the CHCl3 solvate, mp 104°-108°, were obtained from CHCl3 -hexane. An additional 2.7 g of 6c (50% overall yield) was obtained by processing the mother liquor.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04275205 |
| Source dataset | uspto-grants-1981_06 |
| ORD ID | ord-976d795bb88d4985b809eb00d06cd75f |
| Source note | uspto-grants-1981_06 |