Sodium Iodide → 3-Ethyl-6-(3,4-dimethoxyphenyl)-3-hexenyl iodide

HRID 1680752Notes

Reaction equation

HRID 1680752 reaction equation
[CH2:1]([C:3](=[CH:7][CH2:8][CH2:9][C:10]1[CH:15]=[CH:14][C:13]([O:16][CH3:17])=[C:12]([O:18][CH3:19])[CH:11]=1)[CH2:4][CH2:5]Br)[CH3:2].[I-:20].[Na+]>CC(C)=O>[CH2:1]([C:3](=[CH:7][CH2:8][CH2:9][C:10]1[CH:15]=[CH:14][C:13]([O:16][CH3:17])=[C:12]([O:18][CH3:19])[CH:11]=1)[CH2:4][CH2:5][I:20])[CH3:2]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 541546443-Ethyl-6-(3,4-dimethoxyphenyl)-3-hexenyl bromide

Product 1

HCID 544261103-Ethyl-6-(3,4-dimethoxyphenyl)-3-hexenyl iodide

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

3-Ethyl-6-(3,4-dimethoxyphenyl)-3-hexenyl iodide [VI; Ar is 3,4-(CH3O)2C6H3, R is C2H5 ] was prepared from 13.8 g. of 3-ethyl-6-(3,4-dimethoxyphenyl)-3-hexenyl bromide (Preparation C4) and 9 g. of sodium iodide in 120 ml. of acetone, to give 15 g. of product as an oil.

Sources & evidence

ORD record
ord-ac4462dc341b446c840fe76850d287ed
Source dataset
uspto-grants-1981_06
Patent number
US04275201

Reaction notes

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