Dibenzylamine → HCID 23454956, compound

HRID 1680895Notes

Reaction equation

HRID 1680895 reaction equation
[CH2:1]([NH:8][CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:16]([NH:18][NH:19][C:20]1[CH:25]=[CH:24][C:23]([N:26]=[C:27]=[S:28])=[CH:22][CH:21]=1)=[O:17]>C(O)C>[CH:16]([NH:18][NH:19][C:20]1[CH:25]=[CH:24][C:23]([NH:26][C:27]([N:8]([CH2:1][C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[CH2:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[S:28])=[CH:22][CH:21]=1)=[O:17]

Participants

4

Reactant 2

HCID 7656DibenzylamineHCID 20283022N'-(4-Isothiocyanatophenyl)formohydrazide

Product 1

HCID 23454956HCID 23454956, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Dibenzylamine (0.20 g, 0.001 mole) and 4-(2-formylhydrazino)phenyl isothiocyanate (0.19 g, 0.001 mole) were mixed in ethanol (25 ml) and the resulting mixture was heated to reflux for 20 minutes. The reaction mixture was cooled to room temperature, then was chilled in ice. After scratching the flask walls, a white crystalline solid was separated out of solution. The solid was filtered off, washed thoroughly with ether, and allowed to dry. This gave 0.31 g (80 percent) of product as a white crystalline powder, m.p. 174°-176° C.

Workup

  1. temperaturethe resulting mixture was heated
  2. temperatureto reflux for 20 minutes
  3. temperaturewas chilled in ice
  4. customa white crystalline solid was separated out of solution
  5. filtrationThe solid was filtered off
  6. washwashed thoroughly with ether
  7. customto dry

Sources & evidence

ORD record
ord-1f594226463a4f0895c788e4ddef76de
Source dataset
uspto-grants-1981_06
Patent number
US04276364

Reaction notes

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