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HRID1680918

反应详情

EQUATION

反应方程式

HRID 1680918 的结构方程式

REACTANTS

反应物

2
结构：O=C1CCCCC1Cl
HCID13203

2-Chlorocyclohexanone

C6H9ClO

结构：CC(S)C(C)S
HCID548353

2,3-Butanedithiol

C4H10S2

PRODUCTS

生成物

1
结构：CC1SC2=C(CCCC2)SC1C
HCID12920054

2,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine

C10H16S2

收率 49%

PROCEDURE

实验过程

The procedure of Example 1(a) is followed using 2,3-butanedithiol and 2-chlorocyclohexanone to give 5,6,7,8-tetrahydro-2,3-dimethyl-1,4-benzodithian as a greenish oil, b.p. 90°-100°/0.07 mm. Yield 49%. NMR 1.34 (6d), 1.45-2.25 (8m), 2.7-3.1 (2m). IR 2900, 1610, 1435, 1365, 1320, 1115, 795, 690.