Benzaldehyde → HCID 10535817, compound

HRID 1681003Notes

Reaction equation

[CH3:1][C@@H:2]([OH:7])[CH2:3][C@H:4]([OH:6])[CH3:5].[CH:8](=O)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1>>[CH2:8]([O:6][C@H:4]([CH3:5])[CH2:3][C@H:2]([OH:7])[CH3:1])[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1

Participants

Reactant 2

HCID 240Benzaldehyde

HCID 27236832,4-Pentanediol, (-)-

Product 1

HCID 10535817HCID 10535817, compoundYield 107%

Procedure

20.0 g of (2R, 4R)-(-)-pentanediol and 20.4 g of benzaldehyde were subjected to the same procedure as in Example 91 i) to obtain 39.9 g of (2R, 4R)-4-benzyloxy-2-pentanol.

Sources & evidence

ORD record: ord-e268c6d338f647a8a70a772dce21c9de
Source dataset: uspto-grants-1992_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05167863

Reaction notes

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