HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 4-(N-Dodecanoylaminomethyl)-5-hydroxy-2(5H)-furanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Rose Bengal Lactone | HCID 69439 | — |
| Reactant | 4-(N-Dodecanoylaminomethyl)-2-triethylsilylfuran | HCID 15037050 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 4-(N-Dodecanoylaminomethyl)-5-hydroxy-2(5H)-furanone | HCID 15037051 | — |
Reaction Steps
A mixture of 4-(N-dodecanoylaminomethyl)-2-triethylsilylfuran (73.2 mg, 0.18 mmol), water (0.05 ml) and Rose Bengal (ca. 3 mg) in tetrahydrofuran (5 ml) was exposed to singlet oxygen at 0° for 1.5 hours. The residue, after solvent removal, was purified by chromatography on preparative silica thin layer plates (developed with ethyl acetate) to
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05171863 |
| Source dataset | uspto-grants-1992_12 |
| ORD ID | ord-3a7043de3e534af898502be191bf9577 |
| Source note | uspto-grants-1992_12 |